Studies of a new series of ion-pair complexes [Mo(dtc)_4][Ln(dtc)_4] (Ln=La-Er,***)

作     者：FU, Qing-Hong ZHANG, Guang-RenChemistry Division, Logistical Engineering University, Chongqing, Sichuan 630042, ChinaSUN, Chun-Ting NIU, Shu-Yun WU, Li-XinInstitute of Theoretical Chemistry, Jilin University, Changchun, Jilin 130023, China 

作者机构：Chemistry Division Logistical Engineering University Chongqing Sichuan 630042 China Institute of Theoretical Chemistry Jilin University Changchun Jilin 130023 China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：1996年第14卷第3期

页      面：206-210页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学] 

基　　金：Project supported by the National Natural Science Foundation of China 

主　　题：Ion-pair complex molybdenum rare earth metals 

摘      要：A new series of ion-pair complexes [Mo(dtc)4][Ln(dtc)4] (Ln=La-Er, exp. Pm) were synthesized from MoCl5, LnCl3 and Nadtc in anhydrous methanol. The crystal structures of the four complexes, [Mo(dtc)4][Ln(dtc)4] (Ln=Nd, Sm, Ho and Er) have been determined by X-ray diffraction. Spectroscopic properties of all these complexes are also discussed here.