The Construct of A Neutral Medium Applicable Electrochemiluminescent Sensor Based on the Chemical Modification of Cysteine and Luminol
The Construct of A Neutral Medium Applicable Electrochemiluminescent Sensor Based on the Chemical Modification of Cysteine and Luminol作者机构:Institute of Analytical Chemistry College of Chemistry and Chemical Engineering Suzhou University Suzhou 215123 China
出 版 物:《稀有金属材料与工程》 (Rare Metal Materials and Engineering)
年 卷 期:2006年第35卷第A3期
页 面:409-412页
核心收录:
学科分类:08[工学] 0805[工学-材料科学与工程(可授工学、理学学位)]
主 题:electrochemiluminescent sensor chemical modification luminol cysteine sensitization superoxide dismutase
摘 要:In the phosphate buffer solution of pH7,the cysteine sensitized the electrochemiluminescence (ECL) of *** could be modified on the surface of platinum electrode and furthermore adsorbing the luminol on its exterior to construct an ECL *** ECL intensity of this sensor was strong enough and very *** wasn t obvious decrease of ECL intensity for thirty times of using in 48 hours with the relative standard deviation (RSD) of 0.98%.It could be used to determine some quenching effective molecules such as superoxide dismutase (SOD) with negative response upon the concentration range from 4.8 IU/ml to 57.6 IU/ml.