A FACILE APPROACH FOR THE SURFACE MODIFICATION OF POLY(VINYLIDENE FLUORIDE) MEMBRANE VIA SURFACE-INITIATED ATOM TRANSFER RADICAL POLYMERIZATION

作     者：Lei, Hao Yu, Hai-yin Lu, Ying Lu, Xiao-long Xu, Zhi-kang 

作者机构：Zhejiang Univ Minist Educ Inst Polymer Sci Hangzhou 310027 Peoples R China Zhejiang Univ Minist Educ Key Lab Macromol Synth & Functionalizat Hangzhou 310027 Peoples R China Tianjin Polytech Univ Inst Membrane Sci & Technol Ningbo 315211 Peoples R China 

出 版 物：《Chinese Journal of Polymer Science》 (高分子科学（英文版）)

年 卷 期：2008年第26卷第1期

页      面：105-110页

核心收录：

学科分类：08[工学] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：This work was financially supported by the National Natural Science Foundation of China for Distinguished Young Scholars(No. 50625309) the Zhejiang Provincial Natural Science Foundation of China(No. Z406260) 

主　　题：Poly(vinylidene fluoride) Alkaline treatment Bromine addition Atom transfer radical polymerization 

摘      要：A novel approach for the surface modification of poly(vinylidene fluoride)(PVDF)membrane was successfully realized through alkaline treatment,UV-induced bromine addition,and followed by surface-initiated atom transfer radical polymerization(ATRP)of methyl methacrylate(MMA).Chemical changes on the PVDF membrane before and after modification were analyzed with attenuated total reflectance Fourier transform infrared spectroscopy(ATR/FT-IR)and X-ray photoelectron spectroscopy(XPS).Primary kinetic study revealed...