Green,mild and efficient bromination of aromatic compounds by HBr promoted by trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane in water as a solvent
Green,mild and efficient bromination of aromatic compounds by HBr promoted by trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane in water as a solvent作者机构:Department of ChemistryFaculty of ScienceUniversity of Arak Department of ChemistryShahr-e-Rey branchIslamic Azad University
出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))
年 卷 期:2012年第23卷第4期
页 面:387-390页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
主 题:Trans-3 5-dihydroperoxy-3 5-dimethyl-1 2-dioxolane HBr Bromination Anilines Phenoles
摘 要:A combination of HBr and trans-3,5-dihydroperoxy-3,5-dimethyl-1,2-dioxolane as anew and powerful oxidant was found effective for facile brotnination of different aromatic compounds at room temperature in water as a green *** reaction conditions,high selectivity and yield,high reaction rate and non-toxicity are some of the major advantages of this synthetic protocol.