Studies on Silicon-Containing Fragrance Raw Materials( Ⅲ )——The Addition of 5-Trimethylsilylcyclohex-3-enone with Grignard Reagent
Studies on Silicon-Containing Fragrance Raw Materials( Ⅲ )——The Addition of 5-Trimethylsilylcyclohex-3-enone with Grignard Reagent出 版 物:《Chemical Research in Chinese Universities》 (高等学校化学研究(英文版))
年 卷 期:1993年第9卷第1期
页 面:40-44页
核心收录:
基 金:Supported by the National Natural Science Foundation of China Youth Foundation of Tianjin
主 题:5-trimethylsilylcyclohex-3-enone Grignard reagent Addition Stereochemistry
摘 要:The present paper narrates the addition of 5-trimethylsilylcyclohex-3-enone to Grig-nard reagent to give 1-substituted 5-trimethylsilylcyclohex-3-enol in a good yield. The stereochemistry of the addition reaction and their products are discussed.