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Studies on Silicon-Containing Fragrance Raw Materials( Ⅲ )——The Addition of 5-Trimethylsilylcyclohex-3-enone with Grignard Reagent

Studies on Silicon-Containing Fragrance Raw Materials( Ⅲ )——The Addition of 5-Trimethylsilylcyclohex-3-enone with Grignard Reagent

作     者:TANG Shi-xiong, XUE Jie-you, DUAN Mao-shengCAO Yu-rong, ZHI Jin-fang and WANG Xiao-Ian(Department of Chemistry, Nankai University, Tianjin, 300071) 

出 版 物:《Chemical Research in Chinese Universities》 (高等学校化学研究(英文版))

年 卷 期:1993年第9卷第1期

页      面:40-44页

核心收录:

学科分类:07[理学] 0703[理学-化学] 

基  金:Supported by the National Natural Science Foundation of China Youth Foundation of Tianjin 

主  题:5-trimethylsilylcyclohex-3-enone Grignard reagent Addition Stereochemistry 

摘      要:The present paper narrates the addition of 5-trimethylsilylcyclohex-3-enone to Grig-nard reagent to give 1-substituted 5-trimethylsilylcyclohex-3-enol in a good yield. The stereochemistry of the addition reaction and their products are discussed.

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