BAMO聚合物的合成与表征(英文)

作     者：M.V.Maheshkumar M.J.Joseph K.Sreekumar H-G.Ang 

作者机构：Department of Applied Chemistry Cochin University of Science and Technology Cochin-682022 KeralaIndia Energetic Materials Research CentreNanyang Technological University50 Nanyang Avenue Block N1-B4a-02Singapore 639 798 

出 版 物：《含能材料》 (Chinese Journal of Energetic Materials)

年 卷 期：2006年第14卷第6期

页      面：411-415页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

主　　题：有机化学 合成方法 爆炸物 BAMO 

摘      要：A new synthetic methodology has been developed for the synthesis of poly BAMO and poly BAMO-co-THF with controlled molecular weight and narrow molecular weight distribution. The synthesis of BCMO, the precursor of the BAMO monomer was accomplished using the reaction of Vilsmeir reagent with pentaerythritol. The BAMO monomer could be synthesized with an over all yield of 60% and polymerized using BF3·Et2O as the initiator and 1,4-butane diol as the co-initiator. Computational evaluation of the energy releasing properties of the poly BAMO derivatives was performed using Gaussian algorithm. The theoretically calculated values agreed very well with the experimentally determined ones.