Characterization of Dust and Non-dust Aerosols with SEM/EDX

作     者：QI Jianhua LI Xianguo FENG Lijuan ZHANG Manping 

作者机构：College of Environmental Science and Engineering Ocean University of China Qingdao 266003 P. R. China College of Chemistry and Chemical Engineering Ocean University of China Qingdao 266003 P.R. China 

出 版 物：《Journal of Ocean University of China》 (中国海洋大学学报（英文版）)

年 卷 期：2006年第5卷第1期

页      面：85-90页

学科分类：07[理学] 070602[理学-大气物理学与大气环境] 0706[理学-大气科学] 

基　　金：supported by the National Natural Science Foundation of China(Grant No.49976020) 

主　　题：aerosol individual particle scanning electron microscopy 

摘      要：Total suspended particulate （TSP） samples were collected at three sites along the coast of Qingdao, China, before and during a major dust storm in March, 2002. For comparison, PM10（particulate matter with aerodynamic diameters less than 10μm） samples were collected at one of the three sites. The morphological observation and compositional analysis of bulk and individual particles were performed by using scanning electron microscopy equipped with an energy dispersive X-ray system （SEM/EDX） for the TSP and PM10 samples. The results showed that the particles of different kinds of morphology had different elemental compositions, but the particles of similar morphology did not always have the same elemental composition for non-dust samples. The morphology and composition of non-dust particles were different at different sites. The fractal and spherical particles existed mainly in the coarse fraction for non-dust samples, while in the fine mode （〈 10μm） there were floccules formed by fine particles flocking together and containing crustal elements. Compared with the non-dust particles, the dust particles were more homogeneous in terms of morphology, particle size and composition. Particles with irregular shapes and well-distributed sizes dominated in the dust samples, containing crustal elements such as Mg, A1, Si, Ca, Fe, etc. The high sulfur content indicated that homogeneous and heterogeneous reactions took place on the surfaces of the dust particles in the specific environment of Qingdao.