Polarized Emission of Molecular Film With Lanthanide (Ⅲ) Complex
Polarized Emission of Molecular Film With Lanthanide (Ⅲ) Complex作者机构:Deparment of Chemistry and Biological ScienceCollege of Science and EngineeringAoyama Gakuin University
出 版 物:《复旦学报(自然科学版)》 (Journal of Fudan University:Natural Science)
年 卷 期:2007年第46卷第5期
页 面:727-页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学]
主 题:lanthanide complex ff-emission LB film energy transfer heavy metal effect
摘 要:1 Results In the coordination system by using complexation with organic ligand, the ff emission of lanthanide(Ⅲ) (Ln(Ⅲ)) is induced the excitation energy transfer form the organic chromophore under the light-irradiation. However, there are not so much number of reports to discuss the energy relaxation mechanism in such complexes with Ln(Ⅲ). Recently, we succeeded firstly to estimate the rate constant of the energy transfer between the ligand and Ln(Ⅲ) in Pr(Ⅲ)-phenanthroline analogs[1]. Here, we will di...