Supported Cupric Oxide Catalysts for Cyclopropanation of Styrene with Ethyl Diazoacetate

作     者：刘翔 刘艳 等 

作者机构：StateKeyLaboratoryofCatalysisDalianInstituteofChemicalPhysicsTheChineseAcademyofSciencesDalian1160 

出 版 物：《催化学报》 (Chin. J. Catal.)

年 卷 期：2001年第22卷第4期

页      面：319-320页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

主　　题：苯乙烯 重氮乙酸乙酯 环丙烷化反应 氧化铜 二氧化钛 负载型催化剂 催化反应 三氧化二铝 

摘      要：Cyclopropanes are extensively used as versatile intermediates in organic synthes is［1］. Various types of cyclopropanes exist in nature and many of them a re biologically active compounds［2,3］. The direct transfer of carbene fr om diazocompounds to olefins catalyzed by transition metals is the most straight forward route to synthesize cyclopropanes.