Anionic Synthesis of Primary and Secondary Amine-Functionalized Polymers Using Imine Chemistry

作     者：Roderic P.QUIRK, Taejun YOO, Tae-Hee.CHEONG, Youngjoon LEE (Maurice Morton Institute of Polymer Science,The University of Akron, Akron,Ohio,44325-3909,U.S.A.) Dedicated to the Occasion of the 80th Birthday of Prof.HUANG Bao-Tong and Prof.Feng Zhi-Li 

作者机构：The University of Akron 美国 44325-3909 

出 版 物：《应用化学》 (Chinese Journal of Applied Chemistry)

年 卷 期：2001年第18卷第5期

页      面：289-295页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：0 

主　　题：胺功能团 聚合物 亚胺衍生物 阴离子聚合 

摘      要：A review of methods for the anionic synthesis of well-defined, amine-functionalized polymers using imines as functionalizing agents is provided. The disparate results in the literature regarding functionalizations with N -(benzylidene)trimethylsilylamine to form primary amine functionalized polymers are discussed; the efficiency of functionalization depends on the molecular weight of the polymeric organolithium(PLi). Efficient functionalizations are observed for PLi with n10 000 g/mol. The poor functionalization yields using ketimines with enolizable hydrogens is explained. The use of N -trimethylsilyldiphenylcarbimide as a quantitative primary amine functionalizing reagent is described. Recent results on the anionic synthesis of secondary amine-functionalized polymers using N -(benzylidene)methylamine as the functionalization agent are presented.