Synthesis of Fullerene Hydrazine Derivatives

作     者：Shen Shengwen Zhu Ling Yang Dailing Zhang Xungao Sheng Rongsheng 

出 版 物：《Wuhan University Journal of Natural Sciences》 (武汉大学学报（自然科学英文版）)

年 卷 期：1997年第2卷第4期

页      面：107-110页

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

主　　题：fullerene fullerene hydrazine derivative negative ion mass spectra 

摘      要：C 60 /C 70 mixture reacts with hydrazine hydrate catalysed by tetrabutylammonium bromide (TBAB) in the presence of air to afford fullerene hydrazine derivatives C 60 (OH) n(NHNH 2) n and C 70 (OH) n(NHNH 2) n,which are characterized by means of MS and FTIR.A possible reaction mechanism is discussed.