SYNTHESIS,CHARACTERIZATION AND PHOTOLUMINESCENT PROPERTIES OF NEW PLATINUM-CONTAINING POLY(FLUORENYLENEETHYNYLENE) ANCHORED WITH CARBAZOLE PENDANTS
SYNTHESIS,CHARACTERIZATION AND PHOTOLUMINESCENT PROPERTIES OF NEW PLATINUM-CONTAINING POLY(FLUORENYLENEETHYNYLENE) ANCHORED WITH CARBAZOLE PENDANTS作者机构:Department of Chemistry and Centre for Advanced Luminescence MaterialsHong Kong Baptist UniversityWaterloo RoadKowloon Tong Invited lecture presented at the 4(th) International Conference on Photoresponsive Organics and Polymers
出 版 物:《Chinese Journal of Polymer Science》 (高分子科学(英文版))
年 卷 期:2009年第27卷第4期
页 面:455-464页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学]
基 金:supported by the Hong Kong Research Grants Council(No.HKBU202607) Hong KongBaptist University(FRG/06-07/Ⅱ-63)
主 题:Alkyne Carbazole Fluorene Photoluminescence Platinum
摘 要:A new luminescent and thermally stable platinum(Ⅱ) polyyne polymer trans-[-Pt(PBu_3)_2C=CArC=C-]_n(P1) containing the 2,7-fluorene chromophoric spacer substituted by pendant carbazolyl group via long alkyl bridges. The regiochemical structures of these compounds were studied by various spectroscopic *** report the photophysical properties of this group 10 polymetallayne and a comparison was made to its binuclear model complex trans-[Pt(Ph)(PEt_3)_2C≡CArC≡CPt(Ph)(PEt_3)_2](M1) as well as to those wit...