Fabrication of three-dimensional graphene anode for augmenting performance in microbial fuel cells
作者机构:Bioengineering and Environmental Science LabCEEFFCSIR-Indian Institute of Chemical Technology(CSIR-IICT)Hyderabad 500007India Academy of Scientific and Innovative Research(AcSIR)India
出 版 物:《Carbon Resources Conversion》 (碳资源转化(英文))
年 卷 期:2019年第2卷第2期
页 面:134-140页
核心收录:
学科分类:0830[工学-环境科学与工程(可授工学、理学、农学学位)] 081704[工学-应用化学] 0809[工学-电子科学与技术(可授工学、理学学位)] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学] 0836[工学-生物工程] 070301[理学-无机化学]
基 金:wish to thank the Director CSIR-IICT for his encouragement in carrying out this work(IICT/Pubs./2019/039).AP acknowledge funding from Science and Engineering Research Board(National post-doctoral fellow-PDF/2016/001755) DST.JSS acknowledge CSIR for providing research fellowship
主 题:Microbial fuel cell 3D graphene Wastewater treatment Chemical reduction Graphene electrodes
摘 要:In the present work,we have reported the synthesis of 3D graphene structures by simple chemical reduction method for application in microbial fuel cell(MFC)as an *** synthesis procedure includes synthesis of graphene oxide by modified Hummers method followed by simultaneous reduction of graphene oxide and the formation of *** 3D graphene structures are characterized using X-ray diffraction and Raman spectroscopy *** characterization is carried out to study the capacitive properties and impedance studies of electrodes in conductive electrolyte.3D graphene electrodes show remarkably high capacitive current,charge storage and lower charge transfer resistance as estimated through cyclic voltammetry and Nyquist *** order to evaluate the performance of 3D graphene electrodes in MFC,power density and polarization curves are recorded in three configurations by varying terminal electron acceptors(TEA)viz.,dissolved oxygen(MFC-DO),potassium ferricyanide and MFC without TEA(MFC-NDO).3D graphene electrodes exhibits maximum power density of 0.49 mW/m^(2) in potassium ferricyanide followed by MFC-DO(0.36 mW/m^(2))and MFC-NDO(0.34 mW/m^(2)).Present work highlights the viability of chemically synthesized 3D graphene electrodes as an efficient anode material in MFC.