Synthesis, Photophysical Properties and Near Infrared Electroluminescence of 1 （4）,8（11）,15（18）,22（25）-Tetra- （methoxy-phenoxy） phthalocyanine

作     者：白青龙 张春花 程传辉 李万程 王瑾 杜国同 

作者机构：School of Physics and Optoelectronic TechnologyDalian University of TechnologyDalianLiaoning 116024China College of Chemistry and Chemical EngineeringInner Mongglia University for NationalitiesTongliaoNeimenggu 028043China State Key Laboratory on Integrated OptoelectronicsCollege of Electronic Science and EngineeringJilin University2699 Qianjin StreetChangchunJilin 130012China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2012年第30卷第3期

页      面：689-694页

核心收录：

学科分类：081702[工学-化学工艺] 08[工学] 0817[工学-化学工程与技术] 0803[工学-光学工程] 

基　　金：国家自然科学基金 国家教育部高等学校博士学科点专项科研基金 Fundamental Research Funds for the Central Universities 

主　　题：phthalocyanine electroluminescence photophysical properties near infrared 

摘      要：A new soluble phthalocyaine 1 （4）,8（11）, 15（18）,22（25）-tetra-（methoxy-phenoxy）phthalocyanine （MPPc） was synthesized and verified by mass spectrum （MS）, 1H NMR, IR and elemental analysis. The methoxy-phenoxy groups were introduced in order to enhance the solubility of the phthalocyanine. The photophysical and electrolu- minescent properties were investigated. The organic light-emitting diodes （OLEDs） with the structure of ITO/PVK：MPPc（40 nm）/BCP（20 nm）/Alq3（30 nm）/Al were fabricated. Room-temperature near infrared （NIR） electroluminescence （EL） was observed near 891 nm that effectively covered the first optical communication win- dow near 850 nm.