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Preliminary examination of electrochemical and spectroscopic features of trithiocarbonate collectors for sulfide mineral flotation

Preliminary examination of electrochemical and spectroscopic features of trithiocarbonate collectors for sulfide mineral flotation

作     者:R. Du Plessis 1, J.D. Miller 1, J.C.Davidtz 2 1. Department of Metallurgical Engineering, University of Utah, Salt Lake City, Utah 84102, USA 2. Department of Materials Science and Metallurgical Engineering, University of Pretoria, Pretoria 0002 

作者机构:Univ Utah Dept Met Engn Salt Lake City UT 84102 USA Univ Pretoria Dept Met Engn & Mat Sci ZA-0002 Pretoria South Africa 

出 版 物:《中国有色金属学会会刊:英文版》 (Transactions of Nonferrous Metals Society of China)

年 卷 期:2000年第10卷第S1期

页      面:12-18页

核心收录:

学科分类:081902[工学-矿物加工工程] 0819[工学-矿业工程] 08[工学] 

主  题:redox potential trithiocarbonate collector sulfide mineral flotation 

摘      要:The redox potentials of xanthate/dixanthogen (dithiocarbonate/di dithiocarbonate, DTC/(DTC) 2) and trithiocarbonate/di trithiocarbonate (TTC/(TTC) 2) couples have been measured for the potassium salts. The spectroscopic characteristics of these sulfide mineral collectors were determined by FTIR and UV analysis. Electrochemically controlled contact angle measurements at a pyrite surface provided the basis to analyze the effect of the functional group ( O CS 2 versus S CS 2) on the hydrophobic surface state. Results from this preliminary examination are discussed with respect to the nature of collector adsorption and the pyrite flotation response.

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