Photocatalytic Treatment of Waste Water from Rice Husk Alkaline Hydrolysate
Photocatalytic Treatment of Waste Water from Rice Husk Alkaline Hydrolysate作者机构:Far Eastern Federal University Vladivostok 690950Russian Federation Institute of Chemistry Far-Eastern BranchRussian Academy of Sciences Vladivostok 690022 Russian Federation National Scientific Center of Marine Biology Far Eastern BranchRussian Academy of SciencesVladivostok 690041Russian Federation
出 版 物:《Rice science》 (水稻科学(英文版))
年 卷 期:2019年第26卷第4期
页 面:257-260页
核心收录:
学科分类:0710[理学-生物学] 09[农学] 0901[农学-作物学]
主 题:chemical oxygen demand dilution ratio visible spectrum
摘 要:SUMMARY We carried out photocatalytic treatment of a lignin-free solution of rice husk alkaline hydrolysate [pH of 2, chemical oxygen demand (COD) of 12.8 g/L] using photo-Fenton process in the ultraviolet (UV, wavelength of 365 nm) and visible spectrum. Oxidation of lignin was performed at a constant mass ratio of COD:H2O2 as 1:2 and Fe^2+ concentration of 80 mg/L. It was established that for the destruction of alkaline lignin, exposure to visible or UV radiation was necessary. Decolorization efficiency of a lignin-free solution depends on the dilution rate of the solution. The advanced oxidative photo-Fenton process (UV/Н2О2/Fe^2+) made it possible to reduce the color of lignin-free solution at a dilution ratio of 1:5 by 94% of decolorization efficiency, 87% of phenolic compound and 79% of COD. With the help of gas chromatography, the products of lignin destruction were low-toxic and usable.