Synthesis and Crystal Structure of N-(1'-Phenyl-2'-hydroxyethyl)-2,3-naphthylenedicarboximide
Synthesis and Crystal Structure of N-(1'-Phenyl-2'-hydroxyethyl)-2,3-naphthylenedicarboximide作者机构:Key Laboratory of Bioorganic Chemistry and Molecular Engineering of Ministry of EducationCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871P.R.China
出 版 物:《Chemical Research in Chinese Universities》 (高等学校化学研究(英文版))
年 卷 期:2003年第19卷第2期
页 面:160-164页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金:Supported by the National Natural Science Foundation of China(No. 2 0 172 0 0 1)
主 题:Naphthylene Synthesis Amino alcohol Crystal structure
摘 要:N (1 Phenyl 2 hydroxyethyl) 2,3 naphthylenedicarboximide(1a) was obtained by the reaction of 2,3 naphthylenedicarbonitrile with R phenylglycinol. 2,3 Naphthylenedicarboxylic acid, when reacts with thionyl chloride, gives 2,3 naphthalenedicarboxylic acid cyclic anhydride rather than the corresponding 2,3 naphthalenedicarboxylic acid dichloride. The former, when reacts with S leucinol, gives corresponding dicarboximide(1b). The crystal structure of compound 1a was determined by an X ray single crystal diffraction analysis. Compound 1a: C 40 H 30 N 2O 6, F W=634 66, orthorhombic, space group P 2(1)2(1)2(1), a =1 15556(5) nm, b =3 16552(12) nm, c =0 85984(3) nm; α= 90°, β=90°, γ=90°, V =3 1452(11) nm 3, Z=4, \{F(000)=\}1328, D c=1 340 g/cm 3, μ =0 091 mm -1 . Reflections collected/unique, 28053/4068( R int =0 0411); Final R indices : R 1=0 0337, wR 2=0 0687; Largest diff. peak and hole, 248 and \{-222\} e·nm -3 .