Determination of disperse elements in black shale by inductively coupled plasma mass spectrometry
Determination of disperse elements in black shale by inductively coupled plasma mass spectrometry作者机构：Institute of Geochemistry Ore Deposit Open Laboratory Chinese Academy of Sciences Guiyang 550002 China
出 版 物：《Chinese Science Bulletin》 (科学通报(英文版))
年 卷 期：1999年第44卷第S2期
页 面：173-174页
学科分类：081803[工学-地质工程] 08[工学] 0818[工学-地质资源与地质工程]
主 题：disperse elements black shale ICP-MS.
摘 要：THE elements Se, Te, Ge, Re are easily evaporated out when HClO4, HNO3, HF are used as the opendigestion method. There is a great amount of organic and inorganic carbon in black shale, so it is necessary to use oxide acid （HClO4, HNO3） to digest the samples, and the Cl will interfere the determinationof Se and Ge. In this note we reported a simple digestion method for black shale. The sample was digested with HNO3 and HF in PTFE pressure bomb at 190 for 3 h, the rest HF was reacted with HBO, toprotect the introduction system of ICP-MS. After digestion, the samples were determined directly by ICP-MS. So the recoveries were better than the open digestion method. For 50 mg sample,1.5 mL HNO3 and4 drops of HF can completely dissolve black shale. Inductively coupled plasma mass spectrometry has been successfully used for determination of As,Se, Te, Bi in geological materials. In geological and biological samples, the concentrations of ele-
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