The Growth of Latex Particles during the VAc/BA Copolymerization

作     者：秦少雄 QIN Shaoxiong~ 1,2 LIN Jindong~1 WANG Juan~1 ZHANG Xinya~1 CHEN Huanqin~1 (1.School of Chemical and Energy Engineering, South China University of Technology,Guangzhou 510640, China;2.College of Chemistry and Environment Engineering, Yangtze University, Jingzhou 434100, China)

作者机构：School of Chemical and Energy EngineeringSouth China University of TechnologyGuangzhou 510640 ChinaCollege of Chemistry and Environment Engineering Yangtze UniversityJingzhou 434100China 

出 版 物：《Journal of Wuhan University of Technology(Materials Science)》 (武汉理工大学学报（材料科学英文版）)

年 卷 期：2006年第21卷第3期

页      面：86-89页

核心收录：

学科分类：07[理学] 070305[理学-高分子化学与物理] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 0702[理学-物理学] 

主　　题：hydroxyethyl cellulose VAc/ BA latex average particle diameter conversion ratio 

摘      要：The semi-continuous seeded emulsion eopolymerization of vinyl acetate and butyl acrylate was carried out with hydroxyethyl cellulose as a colloid stabilizer. The morphology of the latex particle and the relationship between the reaction time and the average particle diameter and/or the conversion ratio during the polymerization were invstiguted. The experimental results shaw that the morphology of the latex particle possesses the stable sterie construction. In the seeded polymerizution, the average particle diameter of latex decreased while the conversion ratio increased. At the second term of the emulsion copolymerization （the growth stage of particle size）, the latex particle average diameter increased with copolymerization continuously, but the instantaneous conversation ratio was not large, so it was very necessaO to properly prolong the time during the holding temperature stage.