New Developments in the Calorimetry of High-Temperature Materials

作     者：Alexandra Navrotsky 

作者机构：Peter A. Rock Thermochemistry Laboratory & NEAT ORU University of California Davis CA 95616 USA 

出 版 物：《Engineering》 (工程（英文）)

年 卷 期：2019年第5卷第3期

页      面：366-371页

核心收录：

学科分类：07[理学] 08[工学] 

基　　金：the US Department of Energy, Office of Science,Basic Energy Sciences (DE-SC0001089) while that on ultra-ightemperature calorimetry was supported by the National Science Foundation DMR (1506229 and 1835848) 

主　　题：Calorimetry of High-Temperature Materials Developments 

摘      要：1. Introduction Thermodynamics forms the fundamental underpinning of reactivity, transformation, and stability, and controls processes such as synthesis, corrosion and degradation, environmental transport, catalysis, and biological reactivity. In the materials field, the wealth of new compounds, polymorphs, hybrid organic–inorganic hybrid materials and metal organic frameworks, high-entropy alloys, and multiphase and nanophase materials attained by a variety of non-equilibrium synthesis and processing methodologies has outrun the available thermodynamic data, hampering current understanding of synthetic pathways, materials compatibility, and longevity during use, degradation, corrosion, and dissolution, and limiting our understanding of environmental contamination and transport for new materials.