The Synthesis of Glycosyl Phosphite-Pt(II) Complexes

作     者：LingHuaCAO HongYunGAO ChuanJianZHOU YuTingLIU 

作者机构：CollegeofChemistryandChemicalEngineeringXinjiangUniversityUrumqi830046 StateKeyLaboratoryofElements-OrganicChemistryNankaiUniversityTianjin300071 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：2004年第15卷第2期

页      面：171-174页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：国家自然科学基金(29962002) Nankai University State Key Laboratory of Elemento-Organic Chemistry 

主　　题：Glycosyl phosphite metal complex synthesis. 

摘      要：Ethylene glycol phosphorochloridite 1 or catechol phosphorochloridite 2 reacted with isopropylidene derivatives of D-glucose, D-galactose, D-mannose and D-fructose, a series of glycosyl phosphites were obtained. These glycosyl phosphites form optically active complexes with simple Pt (膊) salts. Pt (II) is coordinated to the phosphorus atom, most of the metal complexes are quite stable.