Effect of Steam on the Oxidative Coupling of Methane over La-Ba System Catalysts
Effect of Steam on the Oxidative Coupling of Methane over La Ba System Catalysts出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)
年 卷 期：1997年第13卷第1期
页 面：41-45页
核心收录：
学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学]
主 题：Effect of steam Methane oxidative coupling La Ba system catalysts
摘 要：The influence of steam on catalytic performance for the oxidative coupling of methane(OCM) over Ba 2+ promoted La 2 O 3 catalysts was studied. It was shown that the presence of a suitable amount of steam led to a significant increase of the yield and selectivity to C 2 hydrocarbons, a decrease of selectivity to carbon monoxide and some increase of selectivity to carbon dioxide with increasing the amount of water in the feed was also observed. The activity and selectivity of the catalysts are more sensitive to the effect of steam with the variation of Ba 2+ content in the catalysts at a relatively low temperature(650℃). The comparative experiments for OCM with methane oxygen mixture diluted with nitrogen or steam were carried out in order to investigate the role of steam.
维普期刊数据库
同方期刊数据库