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Gas-liquid phase coexistence and finite-size effects in a two-dimensional Lennard-Jones system

Gas-liquid phase coexistence and finite-size effects in a two-dimensional Lennard-Jones system

作     者:OUYANG WenZe XU ShengHua SUN ZhiWei 

作者机构:Key Laboratory of Microgravity (National Microgravity Laboratory) Institute of Mechanics Chinese Academy of Sciences Beijing 100190 China 

出 版 物:《Chinese Science Bulletin》 (Chin. Sci. Bull.)

年 卷 期:2011年第56卷第26期

页      面:2773-2779页

核心收录:

学科分类:080704[工学-流体机械及工程] 08[工学] 0807[工学-动力工程及工程热物理] 

基  金:supported by the National Natural Science Foundation of China (20903112,10972217) the Knowledge Innovation Program of Chinese Academy of Sciences (KJCX2-YW-L08) 

主  题:有限尺寸效应 气液相 系统 二维 共存 分子动力学模拟 规模效应 临界温度 

摘      要:The gas-liquid phase coexistence in a two-dimensional Lennard-Jones system is investigated using Maxwell construction method together with molecular dynamics *** results of phase coexistence in different truncations of the potential are compared with data obtained from the literature,and the corresponding critical properties *** crossover from Ising-like to mean field behavior is observed and confirmed as the temperature approaches the critical point from *** simulations on systems with different sizes,we find that a finite size effect is more significant than those shown in most of the previous results,and a lower critical temperature is obtained when the full extent of this finite size effect is considered.

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