RADICAL POLYMERIZATION OF N, N-DI(2-2'-METHYL-ACRYLOYLOXY-PROPYL)-PARA-TOLUIDINE FUNCTIONAL MONOMER

作     者：丘坤元 傅杰 QIU Kunyuan FU Jie (Departmnt of Chemistry, Peking University, Beijing)

作者机构：Department of ChemistryPeking UniversityBeijing 

出 版 物：《Chinese Journal of Polymer Science》 (高分子科学（英文版）)

年 卷 期：1989年第7卷第3期

页      面：258-265页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 0817[工学-化学工程与技术] 08[工学] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

主　　题：Functional monomer N N-di(2-2′-methylacryloyloxy-propyl )-p-toluidine Synthesis Radical polymerization Kinetics of polymerization ESR study on the radical intermediates. 

摘      要：Functional monomer (MP)_2PT having tertiary aromatic amino group was systhesized from the reaction of N, N-di (2-hydroxypropyl)-p-toluidine with 2-methyl acryloyl chloride. In the presence of organic peroxide, the radical polymerization of (MP)_2PT in toluene took place. The kinetics of (MP)_2PT polymerization and the ESR spectra of LPO-(MP)2PT-MNP systems were determined respectively.