Ni catalyzed ethylene copolymerization with polar monomers

作     者：Igor E.Soshnikov Changle Chen Konstantin P.Bryliakov 

作者机构：Boreskov Institute of Catalysis Novosibirsk State University Hefei National Laboratory for Physical Sciences at the Microscale CAS Key Laboratory of Soft Matter Chemistry Department of Polymer Science and Engineering University of Science and Technology of China 

出 版 物：《Science China Chemistry》 (中国科学（化学英文版）)

年 卷 期：2019年第62卷第6期

页      面：653-654页

核心收录：

学科分类：07[理学] 0703[理学-化学] 

主　　题：Introduction polyethylene mechanism 

摘      要：Introduction of polar comonomers into polyethylene is highly challenging,paving the way to tuning the copolymers mechanical properties,adhesion/compatibility,and ***-group tolerant single-site palladium and,more tempting,nickel-based catalysts have demon-strated promising reactivities in the ethylene copolymerization with polar comonomers via coordination/insertion mechanism。