STYRENE POLYMERIZATION MEDIATED BY CYCLIC TRITHIOCARBONATE AS RAFT AGENT

作     者：Qi Wang Yi-xian Li Jian Hong Zhi-qiang Fan 

作者机构：Department of Polymer Science ＆ Engineering Zhejiang University Hangzhou 310027 China 

出 版 物：《Chinese Journal of Polymer Science》 (高分子科学（英文版）)

年 卷 期：2006年第24卷第6期

页      面：593-597页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：This work was supported by the National Science Foundation of China (No. 20204013) 

主　　题：Cyclic trithiocarbonate Multiblock polymer RAFT polymerization Styrene. 

摘      要：The novel cyclic trithiocarbonate was synthesized by dialkylation of trithiocarbonate anion with 2,2＇- bis（bromomethyl）biphenyl in a two-phase system using an onium salt as a phase-transfer agent. Styrene polymerization was carried out in the presence of cyclic trithiocarbonate （CTTC）. CTTC undergoes ring opening-polymerization and the incorporated trithiocarbonate moiety derived from CTTC performs as the reversible addition-fragmentation chain transfer （RAFT） agent. Through this mechanism, multiblock polys-tyrenes containing various narrow polydispersity blocks can be prepared.