Synthesis and Crystal Structure of Mn（phen）(PhCOO)2（H2O）

作     者：WANG Wen-Guo CHEN Feng CHEN Chang-Neng LIU Qiu-Tian (State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, The Chinese Academy of Sciences, Fuzhou, Fujian 350002, China) 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学(英文版))

年 卷 期：2003年第4期

页      面：399-402页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：the State Key Basic Research and Development Plan (G1998010100) NNSFC (No. 30170229 and 29973047) 

主　　题：manganese complex crystal structure benzoate 

摘      要：The manganese benzoate complex Mn(phen)(PhCOO)2(H2O) (C26H20MnN2O5) has been synthesized, where phen = 1,10-phenanthroline. The molecular and crystal structures were determined by single-crystal X-ray diffraction. The crystal is of monoclinic, space group P21/c with unit cell parameters: a = 10.7145(7), b = 21.218(1), c = 11.2743(7) ? ?= 117.7342(2), V = 2268.6(3) ?, Z = 4, Mr = 495.38, Dc = 1.450 g/cm3, ?= 0.623 mm-1, F(000) = 1020, T = 293(2) K, R = 0.0563 and wR = 0.1339 for 2468 observed reflections with I 2s(I). In the crystal the manganese atom is five-coordinated by two chelated nitrogen atoms from phenanthroline, three oxygen atoms from two benzoates and one water molecule, completing a triangular bipyramid geometry. The complex exists in a dimer mode by intermolecular hydrogen-bonding interactions.