Characterization and Luminescence Properties of a New Europium(Ⅲ) Complex with a Macrocyclic Ligand

作     者：吴起峰 胡学雷 WU Qifeng,LI Wen,ZHU Zhimeng,WANG Xuan,HU Xuelei*,PAN Zhiquan(Key Laboratory of Green Chemical Process of Ministry of Education-Hubei Key Laboratory of Novel Chemical Reactor and Green Chemical Technology,Wuhan Institute of Technology,Wuhan 430073,China)

作者机构：Key Laboratory of Green Chemical Process of Ministry of Education-Hubei Key Laboratory of Novel Chemical Reactor and Green Chemical TechnologyWuhan Institute of Technology 

出 版 物：《Journal of Wuhan University of Technology(Materials Science)》 (武汉理工大学学报（材料科学英文版）)

年 卷 期：2010年第25卷第6期

页      面：987-990页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：Funded by the Natural Science Founation of Hubei Province (No.2005ABA021) 

主　　题：lanthanide macrocycle crystal structure luminescence 

摘      要：The title compound（13,27-dichloro-3,6,9,17,20,23-hexaazatricyclo-[23.***.1.111,15]-triaconta-l（29）,2,9,11,13,15（30）,16,23,25,27-decaene-29,30-diol-N3,N6,N9,O29,O30）-bis（nitrato-O,O）-Europium（Ⅲ） nitrate was prepared and characterized by elemental analysis,infrared spectra,electrospray mass spectrum and X-ray diffraction,*** crystal of the complex crystallizes in the monoclinic system,space group C2/c with a=2.3737（2） nm,b=14.333（1） nm,c=19.388（2） nm,β = 91.804（1）°,Mr= 850.4,V= 6.5929（8） nm3,R= 0.0333,wR= *** room temperature,excitation of the title complex gives rise to the characteristic luminescent emissions of the Eu3＋ ion.