STUDIES ON CARBOHYDRATES *** STEREOSELECTIVE SYNTHESIS OF 1-O-α-ACYL-D-MANNOPYRANOSE FROM THE CORRESPONDING MANNOSYL TRIMETHYLSILYL ETHER

作     者：He Qing HUANG Zhong Jun LI Meng Shen CAI 

作者机构：School of Pharmaceutical SciencesBeijing Medical UniversityBeijing 100083 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：1995年第6卷第4期

页      面：275-278页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

主　　题：t? 

摘      要：In the presence of ***2, 1-O-trimethylsilyi-2,3,4,6-tetra-O-benzyl-α-D-mannopyranose (1)reacted stereoselectively with a series of carboxylic acids to give the corresponding α-mannosyl carboxylates in good yields. The configuration of products was assigned mainly by 1H-NMR spectra (δH1 and 2J1.2).