Kinetic Study on CO_2 Reforming of Methane

作     者：C.E.Quincoces M.G.González 

作者机构：Centro de Investigacion y Desarrollo en Procesos Cataliticos (CINDECA) 阿根廷 

出 版 物：《Chinese Journal of Chemical Engineering》 (中国化学工程学报（英文版）)

年 卷 期：2001年第9卷第2期

页      面：190-195页

核心收录：

学科分类：0710[理学-生物学] 0830[工学-环境科学与工程（可授工学、理学、农学学位）] 081704[工学-应用化学] 07[理学] 0817[工学-化学工程与技术] 08[工学] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：the Consejo Nacional de Investigacions Cientificas y Tecnicas (CONICET) 

主　　题：CH4 reforming Ni catalysts syngas 

摘      要：The kinetics of CO2 reforming of methane has been studied at 976－1033K on a commercial NiO/CaO/Al2O3 catalyst in a packed-bed continuous reactor. The reaction was carried out at atmospheric pressure and CO2/CH4 ratio 2. The Hougen-Watson rate models were fitted to experimental data assuming the disso ciative adsorption of methane as the rate-determining step. The reaction rate showed an effective reaction order of about unity for CH4. The apparent activity energy was found to be 104 kJ·mol-1. Therefore the kinetic reaction parameters were determined and a possible reaction mechanism was proposed.