Study of Kinetics of Complexation Reaction of Co^(2+) with 2-benzoylpyridine-4-phenyl-3-thiosemicarbazone and Kineticspectrophotometric Determination of Cobalt

作     者：BINGOL.Haluk ATALAY.Tevfik 

作者机构：Faculty of Education Department of ChemistrySelcuk UniversityKonya 42090TurkeyFaculty of EducationDepartment of ChemistrySelcuk UniversityKonya 42090Turkey 

出 版 物：《物理化学学报》 (Acta Physico-Chimica Sinica)

年 卷 期：2006年第22卷第12期

页      面：1484-1488页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：The Project Supported by the Scientific Research Projects (BAP) of Selcuk University  Turkey (EF-2001/064) 

主　　题：钴 动力学研究 缩氨基硫脲 分光谱测量 

摘      要：Kinetics of complexation reaction of Co2+ with 2-benzoylpyridine-4-phenyl-3-thiosemicarbazone(BPPT) was spectrophotometrically examined at 421 *** ligand that is developed for a simple kinetic-spectrophotometric determination of Co2+ is based on 1:2 complex formation between Co2+ and *** complexation reaction was carried out in ethanol-water medium at 25 ℃.Kinetic and activation parameters of the complexation reaction were calculated,and the rate equation and the reaction mechanism were *** calibration graph is linear in the concentration range of 0.10～2.91 mg·L-1 for the tangent *** species that caused interference were investigated.