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Improved hydrogen oxidation reaction under alkaline conditions by Au–Pt alloy nanoparticles

Improved hydrogen oxidation reaction under alkaline conditions by Au–Pt alloy nanoparticles

作     者:Lijuan Lu Lishan Peng Li Li Jing Li Xun Huang Zidong Wei Lijuan Lu;Lishan Peng;Li Li;Jing Li;Xun Huang;Zidong Wei

作者机构:College of Chemistry and Chemical Engineering Chongqing University 

出 版 物:《Journal of Energy Chemistry》 (能源化学(英文版))

年 卷 期:2020年第29卷第1期

页      面:52-56,I0003页

核心收录:

学科分类:0808[工学-电气工程] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术] 

基  金:financially supported by the National Natural Science Foundation of China (Grants no. 21376283  21436003 and 21576032) 

主  题:Hydrogen oxidation reaction Pt-Au alloy Nanoparticles Alkaline electrolyte 

摘      要:This work demonstrates the outstanding performance of alloyed Au1 Pt1 nanoparticles on hydrogen oxidation reaction(HOR)in alkaline *** to the weakened hydrogen binding energy caused by uniform incorporation of Au,the alloyed Au1Pt1/C nanoparticles exhibit superior HOR activity than commercial PtRu/*** the contrary,the catalytic performance of the phase-segregated Au2Pt1/C and Au1Pt1/C bimetallic nanoparticles in HOR is significantly ***,Au1Pt1/C shows a remarkable durability with activity dropping only 4% after 3000 CV cycles,while performance attenuation of commercial PtRu/C is high up to 15% under the same *** results indicate that the alloyed Au1Pt1/C is a promising candidate to substitute commercial PtRu/C for hydrogen oxidation reaction in alkaline electrolyte.

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