Improved hydrogen oxidation reaction under alkaline conditions by Au–Pt alloy nanoparticles
Improved hydrogen oxidation reaction under alkaline conditions by Au–Pt alloy nanoparticles作者机构:College of Chemistry and Chemical Engineering Chongqing University
出 版 物:《Journal of Energy Chemistry》 (能源化学(英文版))
年 卷 期:2020年第29卷第1期
页 面:52-56,I0003页
核心收录:
学科分类:0808[工学-电气工程] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术]
基 金:financially supported by the National Natural Science Foundation of China (Grants no. 21376283 21436003 and 21576032)
主 题:Hydrogen oxidation reaction Pt-Au alloy Nanoparticles Alkaline electrolyte
摘 要:This work demonstrates the outstanding performance of alloyed Au1 Pt1 nanoparticles on hydrogen oxidation reaction(HOR)in alkaline *** to the weakened hydrogen binding energy caused by uniform incorporation of Au,the alloyed Au1Pt1/C nanoparticles exhibit superior HOR activity than commercial PtRu/*** the contrary,the catalytic performance of the phase-segregated Au2Pt1/C and Au1Pt1/C bimetallic nanoparticles in HOR is significantly ***,Au1Pt1/C shows a remarkable durability with activity dropping only 4% after 3000 CV cycles,while performance attenuation of commercial PtRu/C is high up to 15% under the same *** results indicate that the alloyed Au1Pt1/C is a promising candidate to substitute commercial PtRu/C for hydrogen oxidation reaction in alkaline electrolyte.