HIGHLY ACTIVE CATALYSTS FOR CYCLOPROPANATION OF TETRAMETHYLETHYLENE
HIGHLY ACTIVE CATALYSTS FOR CYCLOPROPANATION OF TETRAMETHYLETHYLENE作者机构:CHINESE ACAD SCIDALIAN INST CHEM PHYSDALIAN 116023PEOPLES R CHINA
出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))
年 卷 期:1996年第7卷第8期
页 面:739-740页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
摘 要:Copper(II) Schiff base complexes derived from aromatic amine and salicylaldehyde were found to be highly active catalysts for the cyclopropanation of tetramethylethylene with ethyl diazoacetate. 82% yield of cyclopropanation was obtained with one of the complexes as catalyst.