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Highly ordered arrangement of meso-tetrakis(4-aminophenyl)porphyrin in self-assembled nanoaggregates via hydrogen bonding

Highly ordered arrangement of meso-tetrakis(4-aminophenyl)porphyrin in self-assembled nanoaggregates via hydrogen bonding

作     者:Qing-Yun Liu Qing-Yan Jia Ji-Qin Zhu Qian Shao Jun-Feng Fan Dong-Mei Wang Yan-Sheng Yin 

作者机构:College of Chemistry and Chemical EngineeringOcean University of China College of Chemical and Environmental EngineeringShandong University of Science and Technology Institute of Marine Materials Science and EngineeringShanghai Maritime University 

出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))

年 卷 期:2014年第25卷第5期

页      面:752-756页

核心收录:

学科分类:081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

基  金:financially supported by the National Natural Science Foundation of China(Nos.51042013,21271119) Innovation Fund of Shanghai(No.10170502400) Science Foundation of Shandong Provincial Education Department(No.J08LC11) Research Progect of‘‘SUST Spring Bud’’(No.2008BWZ056) 

主  题:Porphyrin Self assembly Nanoaggregates Highly ordered Hydrogen bonding 

摘      要:meso-Tetrakis(4-aminophenyl)porphyrin(TAPP) can self-assemble into nanostructures with different morphologies by a phase-transfer *** morphologies(nanospheres,nanorods and nanothorns)of porphyrin nanoaggregates could be easily tuned just by changing the concentration of porphyrin in a proper solvent at room *** images revealed the formation of highly ordered supramolecular arrays of TAPP,i.e. superlattice of TAPP molecules in nanoaggregates,which agreed well with the size of one molecule of ***–vis absorption spectra showed an obvious red shift of the Soret band of TAPP,indicating the formation of J-aggregates of TAPP in nanoaggregates.

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