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Preparation and photocatalytic activity of TiO_2 nanoparticles co-doped with Fe and La

Preparation and photocatalytic activity of TiO_2 nanoparticles co-doped with Fe and La

作     者:Zhongliang Shi Xiaoxia Zhang Shuhua Yao 

作者机构:School of Applied Chemistry Shenyang University of Chemical Technology Shenyang 110142 China 

出 版 物:《Particuology》 (颗粒学报(英文版))

年 卷 期:2011年第9卷第3期

页      面:260-264页

核心收录:

学科分类:081705[工学-工业催化] 07[理学] 070205[理学-凝聚态物理] 08[工学] 0817[工学-化学工程与技术] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0702[理学-物理学] 

基  金:supported by the Education Bureau Foundation of Liaoning Province (No. 2008573) the Doctor Foundation of Shenyang Institute of Chemical Technology (No. 20063202) 

主  题:Titanium dioxide Photocatalysis Co doping Phenol 

摘      要:The catalysts of un-doped, single-doped and co-doped titanium dioxide (TiO2) nanoparticles were prepared by a sol-gel method with Ti(OC4H9 )4 as a Ti source material. The photo-absorbance of the obtained nanoparticles was measured by UV-vis diffusive reflectance spectroscopy (UV-vis DRS), and the photocatalytic activity of the prepared samples under UV and visible light was estimated by measuring the degradation rate of phenol (50 mg/L) in an aqueous solution. The effect of Fe and La co-dopants on the material properties was investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM) and N2 adsorption-desorption isotherm measurement. It was shown that the co-doped TiO2 could be activated by visible light and could thus be used as an effective catalyst in photo-oxidation reactions. The photocatalytic activity of TiO2 co-doped with Fe and La is markedly improved due to the synergistic actions of the two dopants.

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