Total Synthesis of (-)-Baimuxifuranic Acid

作     者：Yong Gang CHEN Zhao Ming XIONG Jiong YANG Yu Lin LI(National Laboratory of Applied Organic Chemistry and Institute of Organic Chemistry Lanzhou University,Lanzhou 730000) 

作者机构：LANZHOU UNIVNATL LAB APPL ORGAN CHEMLANZHOU 730000PEOPLES R CHINA LANZHOU UNIVINST ORGAN CHEMLANZHOU 730000PEOPLES R CHINA 

出 版 物：《Chinese Chemical Letters》 (中国化学快报（英文版）)

年 卷 期：1997年第8卷第8期

页      面：697-700页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

主　　题：ppm MHz EIMS Baimuxifuranic Acid Total Synthesis of 

摘      要：The first total synthesis of (-)-baimuxifuranic acid (1) starting from (-)-carvone has been described. In our studies a surprising allylic oxidation was found in the oxidation of alpha beta-unsaturated aldehyde 5 with silver oxide.