Polycyclic Structure Synthesis via a Three-step "[2+n]" Annulation
经由 Threestep 的多不的结构合成[2+n ] 环作者机构:Department of Chemistry Fujian Provincial Key Laboratory of Chemical Biology College of Chemistry and Chemical Engineering Xiamen University Xiamen Fujian 361005 China
出 版 物:《Chinese Journal of Chemistry》 (中国化学(英文版))
年 卷 期:2019年第37卷第5期
页 面:529-530页
核心收录:
主 题:organic agents versatility
摘 要:Carbocycles are ubiquitous in natural organic molecules and medicinal agents. Therefore, developing methodologies for the efficie nt con struction of car bo cycles constitutes an importa nt goal in organic synthesis. In this regard, for the construction of sixmembered rings, the Diels-Alder [4+2] cycloaddition reaction (Figure 1, eq 1) and Robinson annulation (Figure 2, eq 1) represent two paradigms in terms of efficiency, selectivity, and versatility.