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Redox Polymerization of Methyl Methacrylate in the Fluorous Triphasic System

Redox Polymerization of Methyl Methacrylate in the Fluorous Triphasic System

作     者:Shi Zhen CHEN Yun Peng BAI Zhao Long LI 

作者机构:Department of Chemistry Tsinghua University Beijing 100084 

出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))

年 卷 期:2006年第17卷第2期

页      面:258-260页

核心收录:

学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程(可授工学、理学学位)] 0703[理学-化学] 

基  金:Foundation of the central laboratory of the Department of Material  Tsinghua University 

主  题:Fluorous triphasic system redox polymerization methyl methacrylate. 

摘      要:Methyl methacrylate (MMA) was polymerized by using of benzoyl peroxide (BPO) and N, N-dimethylaniline (DMA) as an redox initiator in fluorous triphasic system at room temperature. The polymerization was occurred in both initiator layer and monomer layer in a U-tube. It was found that PMMA obtained from the initiator layer with relatively narrow polydispersity.(PDI = 1.38)

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