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Defluoridation of groundwater by calcined Mg/Al layered double hydroxide

作     者:A.Elhalil S.Qourzal F.Z.Mahjoubi R.Elmoubarki M.Farnane H.Tounsadi M.Sadiq M.Abdennouri N.Barka 

作者机构:Univ Hassan 1Laboratoire des Sciences des Matéeriauxdes Milieux et de la Modélisation(LS3M)BP.14525000 KhouribgaMorocco Equipe de MatériauxPhotocatalyse et EnvironnementDépartement de ChimieFacultédes SciencesUniversitéIbn ZohrB.P.8106 CitéDakhlaAgadirMorocco 

出 版 物:《Emerging Contaminants》 (新兴污染物(英文))

年 卷 期:2016年第2卷第1期

页      面:42-48页

学科分类:081704[工学-应用化学] 07[理学] 070304[理学-物理化学(含∶化学物理)] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 

主  题:Fluoride removal Groundwater Layered double hydroxide Drinking water quality 

摘      要:The present study evaluated calcined Mg/Al layered double hydroxide(CLDH)availability for the removal of fluoride from local *** Mg/Al layered double hydroxide(LDH)was synthesized by coprecipitation method and characterized by XRD,FT-IR and TGA-TDA *** defluoridation experiments were performed under various conditions such as calcination,solution pH,contact time,temperature,material dosage and *** results indicate that fluoride removal strongly increased after calcination of the LDH up to 600℃.The maximum fluoride removal was obtained at solution pH of *** of fluoride removal followed the pseudo-second order kinetic *** rise in solution temperature strongly enhances the removal *** adsorption mechanism involved surface adsorption,ion exchange interaction and original LDH structure reconstruction by rehydration of mixed metal oxides and concomitant intercalation of fluoride ions into the interlayer *** optimum dosages required to meet the national standard for drinking water quality were found to be 0.29 and 0.8 g/L,respectively,for Bejaad and Settat goundwaters.A decrease in the fluoride uptake with increasing the number of regeneration cycles was observed.

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