抗积炭CH_4/CO_2重整用Ni/Al_2O_3催化剂
Ni/Al_2O_3 Catalyst with Repressed Coke Formation in CH_4/CO_2 Reforming作者机构:厦门大学化学系
出 版 物:《应用化学》 (Chinese Journal of Applied Chemistry)
年 卷 期:2000年第17卷第5期
页 面:530-532页
核心收录:
学科分类:081702[工学-化学工艺] 081705[工学-工业催化] 08[工学] 0817[工学-化学工程与技术]
基 金:0
主 题:Ni/Al2O3催化剂 积炭 甲烷 三氧化碳重整 合成气
摘 要:The Ni/Al2O3 catalysts were prepared by two impregnation methods: common and promoted with support salt, for CH4/CO2 reforming and studied by using TPR, TPD, TPMC(Temperature programmed methane decomposition carbon deposition) and activity test techniques. The results showed that the coke formation of the catalysts promoted with support salt(aluminium nitrate) was reduced to one sixth and the dispersion increased by 72.7% in comparison with catalyst prepared by common impregnation method. The interactions between Ni and Al with O on the surface of the support salt promoted catalyst appeared stronger.