新生态二氧化锰的性质及pH值影响除砷效果的研究

作     者：梁慧锋 马子川 刘占牛 LIANG Hui-Feng;MA Zi-Chuan;LIU Zhan-Niu

作者机构：河北师范大学化学学院石家庄050016 邢台学院生化系邢台054001 

出 版 物：《无机化学学报》 (Chinese Journal of Inorganic Chemistry)

年 卷 期：2006年第22卷第4期

页      面：743-747页

核心收录：

学科分类：081704[工学-应用化学] 081705[工学-工业催化] 07[理学] 08[工学] 0817[工学-化学工程与技术] 0703[理学-化学] 070301[理学-无机化学] 

基　　金：国家自然科学基金资助项目(No.20477009) 河北省教育厅科学基金资助项目(No.2004443) 

主　　题：新生态MnO2 机理 表征 静电吸附 离子交换 

摘      要：Fresh MnO2 was prepared by oxide reduction using KMnO4 and MnSO4. The structure and property of the products were characterized by TEM, SEM, XRD and BET, and the effect of pH value was studied on the removal of both As and As. The results show that δ-MnO2 is spherical, its specific surface is 325 m2·g-1 with lots of hydroxyl on the surface. Adsorption of fresh MnO2 of As(III)was a corporate action of both oxide reaction and electrostatic adsorption, but the adsorption of As was due to electrostatic and anion exchange adsorption.