The Synthesis and Structural Characterization of Two-dimensional Coordination Polymer {[Ni(phen)H_2O](μ_4-C_( 10)H_2O_8)_(1/2)}_n

作     者：YE Ling PAN Cheng-ling CHU De-qing WANG Li-min MU Zhong-cheng XU Ji-qing 

作者机构：Key Laboratory for Supramolecular Structure and Materials of Ministry of EducationJilin UniversityChangchun 130023P.R.China College of ChemistryJilin UniversityChangchun 130023P.R.China Department of ChemistryNortheast Normal UniversityChangchun 130024P.R.China 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究(英文版))

年 卷 期：2002年第18卷第4期

页      面：474-477页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

主　　题：Two-dimension Hydrothermal synthesis Inorganic-organic hybrid material Crystal structure 

摘      要：The successful preparation of coordination polymers from modular precursorshas provided a facile approach to develope solids and functional materials. A popular strategy thatcould be employed in the area is the adoption of bridging lig-ands such as cyanide, bi-pyridine,benzenetri-carboxylate, etc. In this context, multi-connecting carboxylates are at presentespecially interesting because they exhibit rich coordination chemistry by coordinating to metalions and have been proved to be a treasury in the design of desired topologies. Althoughbenzenetetracarboxylate ligand is also an excellent bridging reagent, attempts to preparemetal-organic polymeric or supramolecular structures based on this ligand are now rather ***, we have devoted our efforts to assemble new coordination polymers based on this ligand andtransitional metal ions, and obtained a series of novel complexes. We report here the synthesis andstructural characterization of a new compound {[Ni(phen)H_2O] ·(μ_4-C_(10)H_2O_8)_(1/2)}_n(1)exhibiting two-dimensional benzene-tetracarboxylate-Ni (Ⅱ) polymeric layers in the structure.