Syntheses and Characterization of Homochiral Three- dimensional Lanthanide-organic Frameworks Based on Ln_4O_4 Clusters and L-Aspartic Acid

作     者：李新发 刘天赋 高智席 江忠远 

作者机构：Department of ChemistryZunyi Normal College State Key Laboratory of Structural ChemistryFujian Institute of Research on the Structure of MatterChinese Academy of Sciences 

出 版 物：《Chinese Journal of Structural Chemistry》 (结构化学（英文）)

年 卷 期：2011年第30卷第5期

页      面：757-763页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：supported by the Science and Technology Department of Guizhou Province (No. J2121) Zunyi Science and Technology Bureau (No. 04) 

主　　题：homochiral lanthanide cluster amino acid photoluminescence 

摘      要：Four isostructural lanthanide compounds formulated as {[Ln4（μ3-OH）4（L-asp）3- （H2O）10]（ClO4）5·10H2O}n （Ln=Nd （1）, Sm （2）, Eu （3）, Gd （4）; asp=aspartic acid） were synthe- sized by a conventional solution reaction. Their structures were characterized by single-crystal X-ray diffraction, IR spectroscopy and elemental analyses （EA）. It reveals that they crystallize in the chiral P212121 space group. Their structures feature a homochiral three-dimensional （3D） lan- thanide-organic framework, which contains a cubic [Ln4（μ3-OH）4]8＋ cluster sub-building unit （SBU）. Additionally, the photoluminescence property of Eu compound was investigated in the solid-state at room temperature.