Baker's Yeast Mediated Reduction of Optically Active Diketone

作     者：郑国君 高晓蕾 陈锦春 李裕林 

作者机构：State Key Laboratory of Applied Organic Chemistry Institute of Organic Chemistry Lanzhou University Lanzhou Gansu 730000 China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2004年第22卷第2期

页      面：191-193页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：Project supported by the National Natural Science Foundation of China (No. 20272021) 

主　　题：baker抯 yeast reduction agarofuran sesquiterpenoid 

摘      要：Baker抯 yeast mediated reduction of optically active diketone is described. The two keto groups are efficiently dif-ferentiated and the ee value of the recovered material is considerably raised. It affords highly optically active key intermediates efficiently for the synthesis of natural polyhydroxylated agarofuran products.