Baker's Yeast Mediated Reduction of Optically Active Diketone
Baker's Yeast Mediated Reduction of Optically Active Diketone作者机构:State Key Laboratory of Applied Organic Chemistry Institute of Organic Chemistry Lanzhou University Lanzhou Gansu 730000 China
出 版 物:《Chinese Journal of Chemistry》 (中国化学(英文版))
年 卷 期:2004年第22卷第2期
页 面:191-193页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金:Project supported by the National Natural Science Foundation of China (No. 20272021)
主 题:baker抯 yeast reduction agarofuran sesquiterpenoid
摘 要:Baker抯 yeast mediated reduction of optically active diketone is described. The two keto groups are efficiently dif-ferentiated and the ee value of the recovered material is considerably raised. It affords highly optically active key intermediates efficiently for the synthesis of natural polyhydroxylated agarofuran products.