Synthesis and Unexpected Ring-opening Reaction of a New TADDOL Analogue with Chiral Cyclopropane Ring as Backbone
Synthesis and Unexpected Ring-opening Reaction of a New TADDOL Analogue with Chiral Cyclopropane Ring as Backbone作者机构:Department of Applied Chemistry China Agricultural University Beijing 100094
出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))
年 卷 期:2006年第17卷第5期
页 面:606-608页
核心收录:
学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学]
基 金:founded by the National Natural Science Foundation of China(No.20472111)
主 题:TADDOL analogue ring-opening cyclopropane ring synthesis. tetraaryl-1 3-dioxolane-4 5-dimethanol
摘 要:Synthesis and ring-opening reaction of TADDOL analogue with cyclopropane as chiral backbone were described. A plausible ring-opening and carbonium ion rearrangement mechanism have been proposed.