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Synthesis and Unexpected Ring-opening Reaction of a New TADDOL Analogue with Chiral Cyclopropane Ring as Backbone

Synthesis and Unexpected Ring-opening Reaction of a New TADDOL Analogue with Chiral Cyclopropane Ring as Backbone

作     者:Jun LIU Qing Hua BIAN Ming An WANG Hong Chao GUO Min WANG 

作者机构:Department of Applied Chemistry China Agricultural University Beijing 100094 

出 版 物:《Chinese Chemical Letters》 (中国化学快报(英文版))

年 卷 期:2006年第17卷第5期

页      面:606-608页

核心收录:

学科分类:081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基  金:founded by the National Natural Science Foundation of China(No.20472111) 

主  题:TADDOL analogue ring-opening cyclopropane ring synthesis. tetraaryl-1 3-dioxolane-4 5-dimethanol 

摘      要:Synthesis and ring-opening reaction of TADDOL analogue with cyclopropane as chiral backbone were described. A plausible ring-opening and carbonium ion rearrangement mechanism have been proposed.

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