N-Heterocyclic Carbene-Palladium Complex Catalyzed Oxidative Carbonylation of Amines to Ureas

作     者：郑书展 彭新高 刘建明 孙伟 夏春谷 

作者机构：State Key Laboratory for Oxo Synthesis and Selective Oxidation Lanzhou Institute of Chemical Physics Chinese Academic of Sciences Lanzhou Gansu 730000 China Graduate School of the Chinese Academy of Sciences Beijing 100039 China 

出 版 物：《Chinese Journal of Chemistry》 (中国化学（英文版）)

年 卷 期：2007年第25卷第8期

页      面：1065-1068页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070303[理学-有机化学] 0703[理学-化学] 

基　　金：Project supported by the National Natural Science Foundation of China (Nos. 20533080  20625308) 

主　　题：N-heterocyclic carbene oxidative carbonylation urea 

摘      要：Palladium carbene shows high efficiency without any promoter on oxidative carbonylation of amines to ureas and a new type of palladium carbene complex containing both an aniline and an NHC ligands was found to be the active species for the reaction.