Indirect Electrochemical Reduction of Indanthrene Brilliant Green FFB

作     者：江欢欢 葛小芳 徐颖华 张雯雯 马淳安 JIANG Huanhuan;GE Xiaofang;XU Yinghua;ZHANG Wenwen;MA Chunan

作者机构：State Key Laboratory Breeding Base of Green Chemistry-Synthesis Technology College of Chemical Engineering and Materials Zhejiang University of Technology Hangzhou 310032 China Shaoxing Environmental Monitoring Central Station Shaoxing 312000 China 

出 版 物：《Chinese Journal of Chemical Engineering》 (中国化学工程学报（英文版）)

年 卷 期：2011年第19卷第2期

页      面：199-204页

核心收录：

学科分类：081702[工学-化学工艺] 081704[工学-应用化学] 08[工学] 0817[工学-化学工程与技术] 

基　　金：Supported by the National Basic Research Program of China (2003CCA01300) the National Natural Science Foundation of China (20876151) 

主　　题：Indanthrene Brilliant Green FFB indirect electrochemical reduction Fe(III)-triethanolamine cyclic voltammetry 

摘      要：The indirect electrochemical reduction of Indanthrene Brilliant Green FFB （IBG） was investigated in detail by cyclic voltammetry and electrolytic *** （TEA） was used as ligand to form elec-trochemically active Fe（III）-complexes in alkaline *** effects of operating parameters including reaction temperature,current density,concentration of NaOH and Fe（III）-TEA mediator had been studied by orthogonal ex-periments and the mechanism of radicals on electrochemical reduction was *** cyclic voltammetry ex-perimental results show that Fe（III）-TEA complexes are well suited for the indirect electrochemical reduction of *** electrolytic experiments show that high current efficiency （49.9%） can be successfully achieved under op-timized conditions and the current density is found to be the main influence factor.