STUDIES ON SYNTHESES OF MoFe_3S_4 CUBANE-LIKE CLUSTER COMPOUNDS

作     者：刘秋田 康北笙 陈昌能 黄梁仁 蔡进华 庄伯涛 卢嘉锡 LIU QIU-TIAN KANG BEI-SHENG CHEN CHANG-NENG HUANG LIANG=REN CAI JIN-HUA ZHUANG BO-TAO LU JIA-XI (Fufian Institute of Research on-the Structure of Matter, Academia Sinica, Fuzhou)

作者机构：Fufian Institute of Research on-the Structure of Matter Academia Sinica Fuzhou 

出 版 物：《Science China Chemistry》 (中国科学（化学英文版）)

年 卷 期：1989年第32卷第4期

页      面：392-400页

核心收录：

学科分类：07[理学] 0703[理学-化学] 

基　　金：This work was supported by the SFAS 

主　　题：Mo cluster Fe clusters MoFeS clusters heterometallic thiocubane. 

摘      要：The features of synthetic processes are described on the basis of the studies of the syntheses of MoFe_3S_4 cubane-like cluster compounds either by self-assembly reactions or by the conversion of linear clusters. The redox properties and the structure of ligands as well as the stoichiometry of reactants have obvious effects upon the core oxidation state and the structure of products. It is indicated that the self-assembly reaction may pass through a combination process oflinear cluster intermediates having structural unit (M,M =Mo) Fe).