Crystallization Kinetics and Melting Behavior of PA1010/Ether-based TPU Blends

作     者：ZHANG Shu-ling ZHAO Yan SUN Xiao-bo JIANG Zhen-hua WU Zhong-wen WANG Gui-Bin 

作者机构：Alan G. MacDiarmid Lab. College of Chemistry Jilin University Changchun 130012 P. R. China 

出 版 物：《Chemical Research in Chinese Universities》 (高等学校化学研究（英文版）)

年 卷 期：2007年第23卷第3期

页      面：370-373页

核心收录：

学科分类：081704[工学-应用化学] 07[理学] 08[工学] 0817[工学-化学工程与技术] 070305[理学-高分子化学与物理] 080501[工学-材料物理与化学] 0805[工学-材料科学与工程（可授工学、理学学位）] 0703[理学-化学] 

基　　金：Supported by the Science and Technology Council of Jilin Province(No 20020337) 

主　　题：Kinetics Melting point Nylon TPU Differential scanning calorimetry(DSC) 

摘      要：Polyamide 1010 （PA1010）/thermoplastie poly （ether urethane） elastomer （ether-based TPU） blends were prepared via melt extrusion. The crystallization kinetics and melting behavior of PA1010/ether-based TPU blends were systematically investigated using differential scanning calorimetry. The crystallization kinetics results show that the addition of ether-based TPU hinders the crystallization of PA1010, and the hindrance effect increases with the increase of the concentration of ether-based TPU. Both pure PA1010 and PA1010/ether-based TPU blends exhibit double melting peaks in the process of nonisothermal crystallization. The double melting peaks change differently with the variation of cooling rate and blend composition. The cooling rate only influences the lower melting peak; however, the blend composition influences not only the lower melting peak but also the higher melting peak. The reason for the phenomenon must be the interaction between the two compositions.