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Structure and electrochemical performances of as-milled LaMg12-type alloy-Ni composites

作     者:Wen-gang Bi Wei Zhang Jin-liang Gao Yan Qi Dong-liang Zhao Xiao-ping Dong Yang-huan Zhang 

作者机构:Department of Functional Material ResearchCentral Iron and Steel Research InstituteBeijing 100081China Key Laboratory of Integrated Exploitation of Baiyun Obo Multi-Metal ResourcesInner Mongolia University of Science and TechnologyBaotou 014010Inner MongoliaChina Weishan Cisri-Eare Earth Materials Co.LtdJining 277600ShandongChina Department of Mechanical EngineeringHebei UniversityBaoding 071002HebeiChina 

出 版 物:《Journal of Iron and Steel Research International》 (J. Iron Steel Res. Int.)

年 卷 期:2019年第26卷第1期

页      面:59-68页

核心收录:

学科分类:0806[工学-冶金工程] 08[工学] 

基  金:the National Natural Science Foundations of China(51161015 and 51371094) 

主  题:LaMg12 alloy Mechanical milling Ni content Microstructure Hydrogen storage performance 

摘      要:LaMg11Ni+x wt.%Ni(x=100,200)alloys were prepared by ball milling and researched by various methods to study their structure and electrochemical hydrogen storage *** outcomes reveal that increasing Ni content contributes to improving its electrochemical ***,the discharge capacity of as-milled(40 h)alloy will be increased from 157.3 to 1053.5 mAh/g through enhancing Ni percentage from 100 to 200 wt.%when discharging at 60 mAh/*** milling obviously affects the electrochemical performanee of *** milling duration prolonging,the discharge capacity of x=100 alloy keeps increasing,while that of the x=200 alloy has a maximum *** time also affects the cycle stability of experimental *** ng milli ng duration clearly decreases the cycle stability of x=100 alloy but weakens that of the x=200 alloy at first and strengthens it *** addition,prolonging milling time makes the milling prepared x=100 and 200 alloys get the maximal values of high rate discharge ability of 81.60%and 84.52%,respectively.

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